Description : In situ coal gasification poses a potential environmental risk to groundwater pollution although it depends mainly on local hydrogeological conditions. In our investigation, the possible processes of groundwater pollution originating from underground coal gasification (UCG) were analyzed. Typical pollutants were identified and pollution control measures are proposed. Groundwater pollution is caused by the diffusion and penetration of contaminants generated by underground gasification processes towards surrounding strata and the possible leaching of underground residue by natural groundwater flow after gasification. Typical organic pollutants include phenols, benzene, minor components such as PAHs and heterocyclics. Inorganic pollutants involve cations and anions. The natural groundwater flow after gasification through the seam is attributable to the migration of contaminants, which can be predicted by mathematical modeling. The extent and concentration of the groundwater pollution plume depend primarily on groundwater flow velocity, the degree of dispersion and the adsorption and reactions of the various contaminants. The adsorption function of coal and surrounding strata make a big contribution to the decrease of the contaminants over time and with the distance from the burn cavity. Possible pollution control measures regarding UCG include identifying a permanently, unsuitable zone, setting a hydraulic barrier and pumping contaminated water out for surface disposal. Mitigation measures during gasification processes and groundwater remediation after gasification are also proposed.